SYNTHESIS AND X-RAY STRUCTURE OF (-)-[MO(ETA-5-C5ME4-3-PINANYL)(CO)3ME]

被引：9

作者：

LAI, R ^{[1
]}

BOUSQUET, L ^{[1
]}

HEUMANN, A ^{[1
]}

机构：

[1] UNIV MARSEILLE,FAC ST JEROME,URA 1410,ENSSPICAM,F-13013 MARSEILLE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 444卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83063-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the methyl ester of (-)-pinane-3-carboxylic acid 1 with the lithium derivative of 2-brombut-2-ene affords, after dehydration, an isomeric mixture of 3-pinanyl cyclopentadienes 3. Successive treatment with Li(n)Bu, Mo(CO)6 and Mel gives rise to the title complex 5, whose NMR spectra and X-ray structure unambiguously demonstrate the optical integrity and purity of this compound.

引用

页码：115 / 119

页数：5

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