ORGANO-F-ELEMENT THERMOCHEMISTRY - URANIUM LIGAND BOND DISRUPTION ENTHALPIES IN THE (C9H7)3U (C9H7)3U-I (C9H7)3U-CH3 SYSTEM

被引：12
|
作者：
BETTONVILLE, S [1 ]
GOFFART, J [1 ]
FUGER, J [1 ]
机构：
[1] COMMISS EUROPEAN COMMUNITIES,JOINT RES CTR,INST TRANSURANIUM ELEMENTS,W-7500 KARLSRUHE,GERMANY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 393卷 / 02期
关键词：
D O I：
10.1016/0022-328X(90)80200-J
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Uranium-ligand bond disruption enthalpies have been obtained by application of iodinolysis batch-titration solution calorimetry to the (C9H7)3U/(C9H7)3U-I/(C9H7)3U-CH3 system. Derived values in toluene solution are as follows: (C9H7)3U-I, 266.8 ± 3.2 kJ mol-1; (C9H7)3U-CH3, 196.3 ± 6.6 kJ mol-1. The correlation between the latter value and that obtained recently by alcoholysis confirms that the value of D(U-I) is certainly a better parameter for placing D data on an absolute scale than D(U-O). © 1990.
引用
收藏
页码：205 / 211
页数：7
相关论文
共 50 条
  • [1] 2-ELECTRON AND ONE-ELECTRON REDUCTION OF THE INDENYL COMPLEX [MN(ETA(5)-C9H7)(CO)(3)] AND REVERSIBLE COUNTERION-CONTROLLED COMPROPORTIONATION OF [MN(ETA(5)-C9H7)(CO)(3)] AND [MN(ETA(3)-C9H7)(CO)(3)](2-) TO GIVE [MN(ETA(5)-C9H7)(CO)(3)](-)
    LEE, S
    LOVELACE, SR
    COOPER, NJ
    ORGANOMETALLICS, 1995, 14 (04) : 1974 - 1982
  • [2] Monoindenyl titanium alkyl halides. The synthesis and molecular structures of (eta(5)-C9H7)TiBr3, (eta(5)-C9H7)Ti(CH3)Br-2, and (eta(5)-C9H7)Ti(CH3)Cl-2
    Shaw, SL
    Storhoff, JJ
    Cullison, S
    Davis, CE
    Holloway, G
    Morris, RJ
    Huffman, JC
    Bollinger, JC
    INORGANICA CHIMICA ACTA, 1999, 292 (02) : 220 - 224
  • [3] THE FORMATION AND MOLECULAR-STRUCTURE OF [NA(THF)(6)][(ETA(5)-C9H7)(3)PR(MU-CL)PR(ETA(5)-C9H7)(3)]
    YE, ZW
    WANG, SW
    KONG, DY
    HUANG, XY
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 491 (1-2) : 57 - 60
  • [4] Syntheses of indenyl lanthanide derivatives and the molecular structures of [(C9H7)2PrCl(THF)]2 and [(C9H7)3La(THF)]
    Shen, Q
    Qi, MH
    Song, SP
    Zhang, LL
    Lin, YH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 549 (1-2) : 95 - 100
  • [5] Photoionization of Three Isomers of the C9H7 Radical
    Hemberger, Patrick
    Steinbauer, Michael
    Schneider, Michael
    Fischer, Ingo
    Johnson, Melanie
    Bodi, Andras
    Gerber, Thomas
    JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 114 (14): : 4698 - 4703
  • [6] IDENYL CARBAMETALLABORANES .3. THE SYNTHESIS AND CHARACTERIZATION OF NOVEL RHODIUM CARBABORANE COMPOUNDS WITH 3-(C2B9)-8-((C9H6)RH(C9H7))-3,1,2-CLOSO-RHC2B9, 10-((C9H6)RH(C9H7))-7,8-NIDO-C2B9, 9((C9H6)RH(C9H7))-7,8-NIDO-C2B9 AND 3-(ETA-C9H7)-3,1,2-CLOSO-RHC2B9 STRUCTURES
    LEWIS, ZG
    WELCH, AJ
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 438 (03) : 353 - 369
  • [7] GROUP-4 MONO-INDENYL METAL-HALIDES - THE PREPARATION, CHARACTERIZATION, AND REACTIVITY OF (ETA(5)-C9H7)TICL3, [(ETA(5)-C9H7)ZRCL3]X, AND [(ETA(5)-C9H7)HFCL2-MU-CL)]2
    SHAW, SL
    STORHOFF, J
    MORRIS, RJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 116 - INOR
  • [8] (C9H7)2Yb·2THF及（C9H7）2Yb（DME）的合成研究
    蔡瑞芳
    卫景德
    黄祖恩
    刘志
    王文民
    科学通报, 1992, (11) : 1007 - 1009
  • [9] Potential Energy Surface for Oxidation of Indenyl C9H7
    A. R. Ghildina
    A. M. Mebel
    V. N. Azyazov
    Bulletin of the Lebedev Physics Institute, 2018, 45 : 291 - 294
  • [10] Potential Energy Surface for Oxidation of Indenyl C9H7
    Ghildina, A. R.
    Mebel, A. M.
    Azyazov, V. N.
    BULLETIN OF THE LEBEDEV PHYSICS INSTITUTE, 2018, 45 (10) : 291 - 294
12345