INTERCALATION POLYMERIZATION OF THE ANILINIUM CATION IN THE VOPO4 INTERLAYER SPACE

被引：44

作者：

NAKAJIMA, H ^{[1
]}

MATSUBAYASHI, G ^{[1
]}

机构：

[1] OSAKA UNIV, COLL GEN EDUC, INST CHEM, TOYONAKA, OSAKA 560, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Powdered VOPO4 . 2H2O suspended in excess neat aniline gives intercalation compounds VOPO4 . (H2O)x . (PhNH3+)y (0.6<x<1.1; 0.5<y<1.0) with the reduction of the V(V) to V(IV) state. The compounds with y>0.7 lead to the polymerization of the cation by addition of the Cu(II) ion to afford polyaniline. Suspended VOPO4 . 2H2O powders react with PhNH3+Cl-dissolved in ethanol to give the compound intercalated with both the anilinium cation and polyaniline.

引用

页码：423 / 426

页数：4

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