OXIDATION OF WEAKLY ACTIVATED C-H BONDS

被引：34
|
作者：
REISER, O
机构：
[1] Institut für Organische Chemie, Universität Göttingen, D-37077
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 01期
关键词：
D O I：
10.1002/anie.199400691
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The functionalization of hydrocarbons by selective oxidation is of great technical importance. Two new, effective reagents, (perfluoroalkyl)oxaziridines 1a, b, hydroxylate the CH bonds at tertiary C atoms with high selectivity and in good yield. It remains to be seen if they are more economical and efficient than the tried‐and‐true dioxiranes and RuCl3/NaIO4. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：69 / 72
页数：4
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