THE 1ST ALKALINE ALKALINE-EARTH OXOCUPRATE (II, III) - NABA2CU22+CU3+O6

被引：18
|
作者：
TAMS, G [1 ]
MULLERBUSCHBAUM, H [1 ]
机构：
[1] UNIV KIEL,INST ANORGAN CHEM,OLSHAUSENSTR 40-60,W-2300 KIEL 1,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 617卷 / 11期
关键词：
SODIUM; BARIUM; COPPER; OXIDE; CRYSTAL STRUCTURE;
D O I：
10.1002/zaac.19926170103
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound NaBa2Cu3O6 was prepared heating of Na2O2, BaO2, Cu2O in closed Ag-tubes. X-single crystal investigations led to orthorhombic symmetry, space group D2h23-Fmmm; a = 8.4229; b = 11.4418 c = 14.4063 angstrom; Z = 8. Cu2+ and Cu3+ show square planar polygones of four and Na+ trigonal prisms of six O2-. The two barium point positons show coordination numbers C.N. = 8 and 6 + 4. The crystal structure is discussed.
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页码：19 / 22
页数：4
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