CHEMICAL-REACTIONS IN CLUSTERS INDUCED BY LOW-ENERGY ELECTRONS

被引：1
|
作者：
HASHEMI, R
JAFFKE, T
ILLENBERGER, E
机构：
来源：
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1992年 / 96卷 / 09期
关键词：
CHEMICAL BOND; CLUSTERS; ELECTRON SPECTROSCOPY; MOLECULAR INTERACTIONS; NEGATIVE IONS;
D O I：
10.1002/bbpc.19920960912
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electron attachment reactions in pure CF4 clusters and heterogeneous clusters composed of CF2Cl2 and O2 are studied. In the system CF4, effective energy randomization leads to the formation of CF4- monomers which occurs through dissipation of several electronvolts of excess energy among the target aggregate. From the mixed clusters, ions of the form ClO2- and ClO- are generated. ClO- is the result of a complex scattering reaction in the ionized aggregate associated with the cleavage of two chemical bonds and the formation of a new molecule.
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页码：1151 / 1154
页数：4
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