ELECTRONIC-STRUCTURE CONTRIBUTIONS TO FUNCTION IN BIOINORGANIC CHEMISTRY

被引：398

作者：

SOLOMON, EI

LOWERY, MD

机构：

[1] Department of Chemistry, Stanford University, Stanford

来源：

SCIENCE | 1993年 / 259卷 / 5101期

关键词：

D O I：

10.1126/science.8384374

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Many metalloenzymes exhibit distinctive spectral features that are now becoming well understood. These reflect active site electronic structures that can make significant contributions to catalysis. Copper proteins provide well-characterized examples in which the unusual electronic structures of their active sites contribute to rapid, long-range electron transfer reactivity, oxygen binding and activation, and the multielectron reduction of dioxygen to water.

引用

页码：1575 / 1581

页数：7

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