2-Ethoxy-4-(4-methylphenyl)-6-phenylpyridine-3-carbonitrile

被引：2

作者：

Mohamed, Shaaban K. ^{[1
]}

Akkurt, Mehmet ^{[2
]}

Abdelhamid, Antar A. ^{[1
]}

Singh, Kuldip ^{[3
]}

El-Remaily, Mahoud A. A. ^{[4
]}

机构：

[1] Manchester Metropolitan Univ, Chem & Environm Div, Manchester M1 5GD, Lancs, England

[2] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey

[3] Univ Leicester, Dept Chem, Leicester, Leics, England

[4] Sohag Univ, Fac Sci, Dept Chem, Sohag 82524, Egypt

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 15.8; mean σ(C-C) = 0.004 Å; R factor = 0.061; single-crystal X-ray study; T = 150 K; wR factor = 0.157;

D O I：

10.1107/S1600536812032163

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C21H18N2O, crystallized with two independent molecules (A and B) in the asymmetric unit. In molecule A, the central pyridine ring forms dihedral angles of 14.55 (13) and 39.14 (12)degrees with the terminal phenyl and benzene rings, respectively. The latter rings make a dihedral angle of 33.06 (13)degrees with each other. The corresponding values for molecule B are 26.86 (13), 41.82 (12) and 38.99 (13)degrees, respectively. In the crystal, the B molecules are linked via a pair of weak C-H center dot center dot center dot N hydrogen bonds, forming inversion dimers. In addition, C-H center dot center dot center dot pi interactions and pi-pi [centroidcentroid distances = 3.5056 (16) and 3.8569 (17) angstrom] stacking interactions are observed.

引用

页码：02495 / +

页数：12

共 50 条

[1] 2-Ethoxy-6-{(E)-[(4-methylphenyl)imino]-methyl}phenol
Shaheen, Muhammad Ashraf
Tahir, M. Nawaz
Irfan, Rana Muhammad
Iqbal, Shahid
Ahmad, Saeed
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2011 - +
[2] 2-Benzylsulfanyl-4-[( 4-methylphenyl)sulfanyl]-6-pentylpyrimidine-5carbonitrile
El-Emam, Ali A.
Al-Deeb, Omar A.
El-Brollosy, Nasser R.
Ng, Seik Weng
Tiekink, Edward R. T.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2054 - +
[3] Crystal structure of 2-(4-chlorophenyl)-4-(1H-indol-3-yl)-6-phenylpyridine-3-carbonitrile
Vishnupriya, R.
Suresh, J.
Gunasekaran, Pethaiah
Perumal, Subbu
Lakshman, P. L. Nilantha
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O978 - +
[4] 2-Benzyl-6-chloro-1-(4-methylphenyl)-1H-indole-3-carbonitrile
Yan, Qiao
Qi, Xiuxiang
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3388 - U1870
[5] 4′-(4-methylphenyl)-2,2′:6′,2"-terpyridine
Liu, Han-Guo
Qiu, Yong-Cai
Wu, Jian-Zhong
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4876 - U6631
[6] 2-Amino-4-(4-methylphenyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile
Mohamed, Shaaban K.
Akkurt, Mehmet
Tahir, Muhammad N.
Abdelhamid, Antar A.
Albayati, Mustafa R.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02315 - +
[7] 6-(4-Bromophenyl)-2-ethoxy-4-(4-ethoxyphenyl)nicotinonitrile
Chantrapromma, Suchada
Fun, Hoong-Kun
Suwunwong, Thitipone
Padaki, Mahesh
Isloor, Arun M.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O79 - U1736
[8] 6-(4-Bromophenyl)-2-ethoxy-4-(2,4,6-trimethoxyphenyl)nicotinonitrile
Chantrapromma, Suchada
Fun, Hoong-Kun
Suwunwong, Thitipone
Padaki, Mahesh
Isloor, Arun M.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2914 - U2311
[9] 4-(4-Fluoro-3-phenoxyphenyl)-6-(4-fluorophenyl)-2-oxo-1,2-dihydropyridine-3-carbonitrile and the 6-(4-methylphenyl)-analogue
Chopra, D.
Mohan, T. P.
Vishalakshi, B.
Row, T. N. Guru
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2006, 62 : O540 - O543
[10] 6-(4-Aminophenyl)-2-ethoxy-4-(2-thienyl)nicotinonitrile
Fun, Hoong-Kun
Chantrapromma, Suchada
Kobkeatthawin, Thawanrat
Padaki, Mahesh
Isloor, Arun M.
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1811 - U661

← 1 2 3 4 5 →