ELECTRON-PARAMAGNETIC RESONANCE AND INDO-MO STUDIES OF 2-METHYLBUTANE, 3-METHYLPENTANE AND 3-METHYLHEXANE CATIONS PRODUCED IN SEVERAL HALOCARBON MATRICES GAMMA-IRRADIATED AT 77-K

被引：2
|
作者：
OHTA, N [1 ]
SHIOTANI, M [1 ]
ICHIKAWA, T [1 ]
机构：
[1] HIROSHIMA UNIV,DEPT APPL PHYS & CHEM,HIGASHI,HIROSHIMA 724,JAPAN
来源：
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 24期
关键词：
D O I：
10.1039/ft9918703869
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The EPR results of the selectively deuteriated solute cations 2-methylbutane, 3-methylpentane and 3-methylhexane (2MB+, 3MP+ and 3MHX+) produced in halocarbon matrices (perfluoro-2-methylpentane, CFCl3, CF2ClCFCl2, CF2BrCF2Br and CF2BrCFBrCl) have been studied by means of INDO-MO calculations. The structures of the cations were found to depend on the matrix. The INDO method has shown that the structural changes can be reasonably interpreted on the basis of the structures of 2MB+.
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页码：3869 / 3874
页数：6
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