ZIRCONA[1]METALLOCYCLOPHANES - SYNTHESIS, PROPERTIES, AND STRUCTURE OF (TBU-ETA(5)-C5H4)(2)ZR(ETA(1)-1,ETA(1)-1')(ETA(6)-C6H5)(2)V AND ITS CHROMIUM ANALOG

被引：35
|
作者：
ELSCHENBROICH, C
SCHMIDT, E
METZ, B
HARMS, K
机构：
[1] Fachbereich Chemie der Philipps-Universität
来源：
ORGANOMETALLICS | 1995年 / 14卷 / 09期
关键词：
D O I：
10.1021/om00009a005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tilt caused by the one-atom interannular bridge in a zirconocene unit in 7 imposed at bis(eta(6)-benzene)vanadium (3(.)) is very small. As judged from EPR spectroscopy, the electronic structure of 3(.) is virtually unaffected by zircona[1]vanadocyclophane formation. The novel binuclear complexes are very robust thermally but quite labile chemically. The latter property precludes a thorough electrochemical study of metal-metal interaction in 7(.).
引用
收藏
页码：4043 / 4045
页数：3
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