CHEMISORPTION OF OXYGEN BY ALUMINIUM

被引：45

作者：

ROBERTS, MW

WELLS, BR

机构：

[1] School of Chemistry, The University of Bradford, Bradford 7, Yorkshire England

来源：

SURFACE SCIENCE | 1969年 / 15卷 / 02期

关键词：

D O I：

10.1016/0039-6028(69)90155-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The variation in the work function of aluminium films during oxygen interaction has enabled information to be obtained relating to the stability of chemisorbed oxygen and its subsequent incorporation into the sub-surface region. At both -195 °C and -183 °C chemisorbed oxygen is incorporated; the activation energy of the thermally induced process occurring from the completed oxygen monolayer is ≤3 kcal mole-1. At 23 °C two distinct kinds of behaviour were observed with oxygen; either very little change in work function or a substantial increase (0.6 eV). The present data are discussed with particular relation to the recent results and conclusions of Huber and Kirk. © 1969.

引用

页码：325 / &

共 12 条

[1] THE CALORIMETRIC DETERMINATION OF THE HEATS OF ADSORPTION OF OXYGEN ON EVAPORATED METAL FILMS [J].

BRENNAN, D ;

HAYWARD, DO ;

TRAPNELL, BMW .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1960, 256 (1284) :81-105

[2] ADSORPTION AND OXIDE FORMATION ON ALUMINIUM FILMS [J].

ELEY, DD ;

WILKINSON, PR .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1960, 254 (1278) :327-342

[3] CHEMISORPTION OF OXYGEN ON GOLD [J].

FORD, RR ;

PRITCHARD, J .

CHEMICAL COMMUNICATIONS, 1968, (07) :362-+

[4]

HEYNE H, 1967, INT S SURFACE PHENOM

[5] CHANGES IN WORK FUNCTION OF ALUMINUM DURING AND FOLLOWING LOW PRESSURE OXIDATION AT ROOM TEMPERATURE [J].

HUBER, EE ;

KIRK, CT .

SURFACE SCIENCE, 1967, 8 (04) :458-&

[6] WORK FUNCTION CHANGES DUE TO CHEMISORPTION OF WATER AND OXYGEN ON ALUMINUM [J].

HUBER, EE ;

KIRK, CT .

SURFACE SCIENCE, 1966, 5 (04) :447-&

[7] PREPARATION AND PROPERTIES OF CLEAN SURFACES OF ALUMINUM [J].

JONA, F .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1967, 28 (11) :2155-&

[8] ADSORPTION OF OXYGEN ON THE (111), (100) AND (110) SURFACES OF CLEAN NICKEL [J].

MACRAE, AU .

SURFACE SCIENCE, 1964, 1 (04) :319-348

[9] CHEMISORPTION OF OXYGEN + SUBSEQUENT PROCESSES ON METAL FILMS - WORK FUNCTION MEASUREMENTS [J].

QUINN, CM ;

ROBERTS, MW .

TRANSACTIONS OF THE FARADAY SOCIETY, 1964, 60 (4975) :899-&

[10] CHEMISORPTION AND INCORPORATION OF OXYGEN BY NICKEL FILMS [J].

ROBERTS, MW ;

WELLS, BR .

TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (522P) :1608-&

← 1 2 →