REDUCTION OF ALPHA-DIKETONES AND ALPHA-KETO ESTERS WITH HI IN ACETIC ANHYDRIDE-ACETIC ACID

被引：6
|
作者：
ZOELLER, JR
ACKERMAN, CJ
机构：
[1] Research Laboratories, Eastman Chemicals Division, Eastman Kodak Company, Kingsport
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 04期
关键词：
D O I：
10.1021/jo00291a049
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reduction of a-keto-substituted carbonyl compounds by aqueous Hi-acetic acid solutions has been known for a long time.-1-4With the notable exception of the reduction of benzil derivatives, which cleanly generate benzoins upon reduction, the reaction has been reported to result in the net deoxygenation of the reduced carbonyl according to eq 1. a-Hydroxy ketones are rarely observed. © 1990, American Chemical Society. All rights reserved.
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页码：1354 / 1356
页数：3
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