A CONVERTER FOR PRODUCING A HYDROGEN-CONTAINING SYNTHESIS GAS

被引：3
|
作者：
Malkov, Yu. P. [1 ]
Molchanov, O. N. [1 ]
Britov, B. K. [1 ]
Fedorov, I. A. [1 ]
机构：
[1] Russian Sci Ctr Appl Chem, 26A Krylenko Str, St Petersburg 193232, Russia
来源：
JOURNAL OF ENGINEERING PHYSICS AND THERMOPHYSICS | 2016年 / 89卷 / 06期
关键词：
converter; reactor; catalyst; hydrogen-containing synthesis gas; hydrocarbon fuel; thermal-oxidative and steam conversions;
D O I：
10.1007/s10891-016-1525-2
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A computational thermodynamic and experimental investigation of the characteristics of a model of a converter for producing a hydrogen-containing synthesis gas from a hydrocarbon fuel (kerosene) with its separate delivery to thermal-oxidative and steam conversions has been carried out. It is shown that the optimum conditions of converter operation correspond to the oxidant excess coefficient in the converter's combustion chamber a >0.5 at a temperature of the heat-transmitting wall (made from a heat-resistant KhN78T alloy (EI 435)) of 1200 K in the case of using a nickel corrugated tape catalyst. The content of hydrogen in the synthesis gas attains in this case 60 vol.%, and there is no release of carbon (soot) in the conversion products as well as no need for water cooling of the converter walls.
引用
收藏
页码：1545 / 1553
页数：9
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