ACTIVITY AND SELECTIVITY OF NIPT/SIO2 CATALYSTS FOR HYDROGENATION OF CROTONALDEHYDE

被引：58
|
作者：
RAAB, CG [1 ]
LERCHER, JA [1 ]
机构：
[1] VIENNA TECH UNIV,CHRISTIAN DOPPLER LAB HETEROGENE KATALYSE,A-1060 VIENNA,AUSTRIA
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 75卷 / 01期
关键词：
D O I：
10.1016/0304-5102(92)80104-O
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The hydrogenation of crotonaldehyde over a series of Pt/Ni catalysts was investigated. While the rate of hydrogenation to butyraldehyde was a monotonic function of the Ni concentration, the rate to crotyl alcohol was related to the concentration of the PtNi alloy. The selectivity to hydrogenation of the carbonyl group was attributed to the presence of polar surfaces (negatively charged Pt and positively charged Ni). Two independent sites, catalyzing the hydrogenation of crotonaldehyde to butyraldehyde and to crotyl alcohol, were established.
引用
收藏
页码：71 / 79
页数：9
相关论文
共 50 条
  • [1] Co/SiO2 catalysts for selective hydrogenation of crotonaldehyde II:: influence of the Co surface structure on selectivity
    Rodrigues, EL
    Bueno, JMC
    APPLIED CATALYSIS A-GENERAL, 2002, 232 (1-2) : 147 - 158
  • [2] Reaction Induced Selectivity Improvement in the Hydrogenation of Crotonaldehyde over Sn-@Pt/SiO2 Catalysts
    Margitfalvi, J. L.
    Tompos, A.
    Kolosova, I.
    Valyon, J.
    Journal of Catalysis, 174 (02):
  • [3] Reaction induced selectivity improvement in the hydrogenation of crotonaldehyde over Sn-Pt/SiO2 catalysts
    Margitfalvi, JL
    Tompos, A
    Kolosova, I
    Valyon, J
    JOURNAL OF CATALYSIS, 1998, 174 (02) : 246 - 249
  • [4] Liquid phase hydrogenation of crotonaldehyde over Pt/SiO2 catalysts
    Englisch, M
    Ranade, VS
    Lercher, JA
    APPLIED CATALYSIS A-GENERAL, 1997, 163 (1-2) : 111 - 122
  • [5] Catalysis of CuB/SiO2 Catalysts for hydrogenation of furfural, crotonaldehyde, and citral
    Liaw, BJ
    Lee, MS
    Chen, YZ
    JOURNAL OF THE CHINESE INSTITUTE OF CHEMICAL ENGINEERS, 2003, 34 (06): : 667 - 674
  • [6] Selective hydrogenation of crotonaldehyde on Pt/ZnCl2/SiO2 catalysts
    Ammari, F
    Milone, C
    Touroude, R
    JOURNAL OF CATALYSIS, 2005, 235 (01) : 1 - 9
  • [7] ACTIVITY AND SELECTIVITY OF PTNI/TIO2 CATALYSTS FOR HYDROGENATION OF CROTONALDEHYDE
    RAAB, CG
    LERCHER, JA
    CATALYSIS LETTERS, 1993, 18 (1-2) : 99 - 109
  • [8] Crotonaldehyde hydrogenation over bimetallic Rh-Sn/SiO2 catalysts
    Reyes P.
    Reaction Kinetics and Catalysis Letters, 2005, 84 (2): : 351 - 358
  • [9] Crotonaldehyde hydrogenation over bimetallic Rh-Sn/SiO2 catalysts
    Aguirre, MD
    Fierro, JLG
    Reyes, P
    REACTION KINETICS AND CATALYSIS LETTERS, 2005, 84 (02): : 351 - 358
  • [10] Cinnamaldehyde Hydrogenation Over Ir/SiO2 and Ir/FeOx/SiO2 Catalysts Effect of FeOx on the Activity and Selectivity
    Martinez, Jose J.
    Rojas, Hugo
    Castaneda, Claudia
    Diaz, Gabriela
    Gomez-Cortes, Antonio
    Arenas-Alatorre, Jesus
    CURRENT ORGANIC CHEMISTRY, 2012, 16 (23) : 2791 - 2796
12345