USE OF NAPHTHALENE AS A SOLVENT FOR SELECTIVE FORMATION OF THE 1/1 DIELS-ALDER ADDUCT OF C-60 WITH ANTHRACENE

被引：117
|
作者：
KOMATSU, K
MURATA, Y
SUGITA, N
TAKEUCHI, K
WAN, TSM
机构：
[1] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG
[2] KYOTO UNIV,GRAD SCH ENGN,DIV ENERGY & HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期
关键词：
D O I：
10.1016/S0040-4039(00)61362-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A reaction of C-60 with an equimolar amount of anthracene in refluxing naphthalene gives the 1:1 Diels-Alder adduct in 67% yield based on consumed C-60: the adduct was fully characterized by IR, UV-vis, H-1 and C-13 NMR, and MS spectroscopy, and exhibited reversible reduction waves at the potential 0.11 to 0.19 V more negative and an irreversible oxidation peak at the potential 0.11 V less positive than those of C-60 itself.
引用
收藏
页码：8473 / 8476
页数：4
相关论文
共 50 条
  • [1] A DIELS-ALDER ADDUCT OF C-60 CONTAINING HYDROXYQUINONE FUNCTIONALITIES
    BIDELL, W
    DOUTHWAITE, RE
    GREEN, MLH
    STEPHENS, AHH
    TURNER, JFC
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (14) : 1641 - 1642
  • [2] ISOLATION AND CHARACTERIZATION OF DIELS-ALDER ADDUCTS OF C-60 WITH ANTHRACENE AND CYCLOPENTADIENE
    TSUDA, M
    ISHIDA, T
    NOGAMI, T
    KURONO, S
    OHASHI, M
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (16) : 1296 - 1298
  • [3] SYNTHESIS AND X-RAY STRUCTURE OF A DIELS-ALDER ADDUCT OF C-60
    RUBIN, Y
    KHAN, S
    FREEDBERG, DI
    YERETZIAN, C
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (01) : 344 - 345
  • [4] ELECTROSPRAY MS STUDIES OF C-60 DIELS-ALDER CHEMISTRY - CHARACTERIZATION OF A C-60 ADDUCT WITH THE DANISHEFSKY DIENE
    WILSON, SR
    LU, QY
    TETRAHEDRON LETTERS, 1993, 34 (50) : 8043 - 8046
  • [5] FACIAL SELECTIVITY IN C-60 DIELS-ALDER REACTIONS
    LU, QY
    WILSON, SR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 380 - ORGN
  • [6] Diels-Alder adduct of C70Ph8 with anthracene
    Univ of Sussex, Brighton, United Kingdom
    Fullerene Sci Technol, 4 (643-651):
  • [7] The Diels-Alder adduct of C70Ph8 with anthracene
    Avent, AG
    Birkett, PR
    Darwish, AD
    Kroto, HW
    Taylor, R
    Walton, DRM
    FULLERENE SCIENCE AND TECHNOLOGY, 1997, 5 (04): : 643 - 651
  • [8] OPTICAL-SPECTRA OF DIELS-ALDER ADDUCTS OF C-60
    UDVARDI, L
    SURJAN, PR
    KURTI, J
    PEKKER, S
    SYNTHETIC METALS, 1995, 70 (1-3) : 1377 - 1378
  • [9] AN AM1 STUDY OF THE REACTIVITY OF BUCKMINSTERFULLERENE (C-60) IN A DIELS-ALDER MODEL REACTION
    SOLA, M
    MESTRES, J
    MARTI, J
    DURAN, M
    CHEMICAL PHYSICS LETTERS, 1994, 231 (2-3) : 325 - 330
  • [10] KINETIC STABILITY OF THE C-60-CYCLOPENTADIENE DIELS-ALDER ADDUCT
    GIOVANE, LM
    BARCO, JW
    YADAV, T
    LAFLEUR, AL
    MARR, JA
    HOWARD, JB
    ROTELLO, VM
    JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (33): : 8560 - 8561
12345