NON-STATISTICAL UNIMOLECULAR CHEMICAL-REACTION - ISOMERIZATION OF STATE-SELECTED ALLYL ISOCYANIDE

被引：135

作者：

REDDY, KV

BERRY, MJ

机构：

[1] Corporate Research Center, Allied Chemical Corporation, Morristown

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 02期

关键词：

D O I：

10.1016/0009-2614(79)85003-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Intracavity cw dye laser techniques have been used to measure visible (520-770 nm) absorption spectra of gaseous allyl isocyanide and to photoactivate this unimolecular reactant with bond selectivity using CH stretch overtone excitations. Measurements of photoisomerization kinetics over an extended reactant energy range (170-240 kJ mole-1) indicate that the unimolecular state coefficient is probably nonstatistical and a function of the reactant state(s). © 1979.

引用

页码：223 / 229

页数：7

共 26 条

[1]

BRAY RM, UNPUBLISHED

[2] TRAJECTORY STUDIES OF ENERGY-TRANSFER - CH3NC WITH HE, XE, H2 AND N2 [J].