THE FIRST SYNTHESIS AND DETERMINATION OF ABSOLUTE STEREOCHEMISTRY OF CLONOSTACHYDIOL .2.

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作者
RAO, AVR
MURTHY, VS
SHARMA, GVM
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O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first total synthesis of clonostachydiol has been achieved from two appropriately protected hydroxy acids that are derived from (D)-xylose and 1,2-O-isopropylidene (D)-glyceraldehyde. This synthesis has proved the absolute configuration of four stereocenters in clonostachydiol as 2R,3S,8R,11R unambiguously.
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页码:143 / 146
页数:4
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