VIBRATIONAL AND ROTATIONAL-EXCITATION IN COLLISIONS OF DIATOMIC-MOLECULES WITH RIGID SURFACES

被引：1
|
作者：
SPOHR, E
WOLFSBERG, M
机构：
[1] Institute of Surface and Interface Science, Department of Chemistry, University of California, Irvine, Irvine
来源：
CHEMICAL PHYSICS LETTERS | 1990年 / 165卷 / 2-3期
关键词：
D O I：
10.1016/0009-2614(90)85432-C
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The disappearance of the rotational rainbow in the scattering of unexcited diatomic molecules from a smooth rigid surface due to initial vibrational and rotational excitation and surface corrugation has been studied by classical trajectory calculations. The ratio of vibrational to rotational excitation in initially unexcited molecules strongly increases with increasing impact energy and increasing surface hardness. © 1990.
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页码：221 / 225
页数：5
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