A STUDY ON CH5O+ IONS IN GAS PHASE CID EYPERIMENT AND QUANTUM CHEMISTRY CALCULATION

被引：1

作者：

Guo Chunxiao ^{[1
]}

Hou Dongyan ^{[1
]}

Liu Shuying ^{[2
]}

机构：

[1] Jilin Univ, Dept Chem, Changchun 130023, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, Beijing 100864, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1991年 / 7卷 / 04期

关键词：

CH5O+; CID; MNDO;

D O I：

10.3866/PKU.WHXB19910409

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structures of CH5O+ from two different reactions which are protonation of CH3OH from the above two pathways possess the same structures, CH3OH2+. The value of kinetic energy release for the metastable decomposition CH2OH3+-> CH2OH+ + H-2 determined from the experiment is in good agreement with that from theoretical calculations. The transition state of above reaction were disscussed.

引用

页码：420 / 424

页数：5

共 4 条

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[3] MM-ZAB-2F DOUBLE-FOCUSSING MASS-SPECTROMETER AND MIKE SPECTROMETER
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[J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1978, 28 (02): : 171 - 191
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