Solvent dependence of the emission from species consisting of two identical moieties

被引：65

作者：

Beens, Henk ^{[1
]}

Weller, Albert

机构：

[1] Vrije Univ Amsterdam, Chem Laboratorium, Amsterdam, Netherlands

[2] Max Planck Inst Spektroskopie, Gottingen, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 09期

关键词：

D O I：

10.1016/0009-2614(69)87004-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The role of the solvent with respect to the energy of the lowest excited state of molecules or complexes. which consist of two identical moieties, is investigated by means of a simple model. It is found that at sufficiently high solvent polarities there exist energy minima corresponding to solvated polar (and, therefore, unsymmetrical) species which are more stable than the non-polar symmetrical ones. These theoretical results can account for some experimental findings presently available.

引用

页码：666 / 668

页数：3

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