VIBRATIONAL-SPECTRA AND STRUCTURE OF N,N-DINITROMETHYLAMINE

被引:2
|
作者
AVAKYAN, VG
SHLYAPOCHNIKOV, VA
FEDOROV, BS
MARGOLIN, VN
VOLKOVA, VV
机构
[1] ND ZELINSKII INST ORGAN CHEM,MOSCOW 117913,RUSSIA
[2] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
[3] SCI RES INST PLANT PROTECT CHEM,MOSCOW 109088,RUSSIA
关键词
NITRAMINES; VIBRATIONAL SPECTRA; N; N-DINITROMETHYLAMINE;
D O I
10.1007/BF00714426
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The vibrational (IR and Raman) spectra of N,N-dinitromethylamine were studied. The assignments of the bands were carried out using a comparison of spectra obtained in different aggregate states, invoking the results of normal coordinate analysis. The most probable symmetry of the molecule was shown to be C-S with a planar configuration of the N(NO2)(2) moiety.
引用
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页码:1444 / 1448
页数:5
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