EQUATORIAL AXIAL INTERACTIONS OF LIGANDS AND PHOTOCHEMICAL PROPERTIES OF CO(III) COMPLEXES CONTAINING TETRADENTATE LIGANDS

被引：0
|
作者：
SIMA, J
GRIB, L
JALCOVIKOVA, V
机构：
来源：
CHEMICAL PAPERS | 1991年 / 45卷 / 03期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The paper presents the results of the photochemical studies of the complexes trans-[Co(L(eq))(L(ax))2]X in methanol, where L(eq) = N,N'-ethylene-bis(acetylacetoniminato) or N,N'-ethylenebis(salicylideniminato) dianion; L(ax) = NH3 or pyridine; X- = Cl- or NCS-. The phenomenon of equatorial -axial interactions of ligands via the central atom in complexes forms the basis on which the results are interpreted.
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页码：303 / 312
页数：10
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