SYNTHESIS AND PROPERTIES OF (+/-)-4-MES-3-C2H5-1,2,3-C2COB9H10 AND (+)-4-MES-3-C2H5-1,2,3-C2COB9H10

被引：25

作者：

PLESEK, J ^{[1
]}

GRUNER, B ^{[1
]}

MALON, P ^{[1
]}

机构：

[1] ACAD SCI CZECH REPUBLIC, INST ORGAN CHEM & BIOCHEM, CS-16610 PRAGUE 6, CZECHOSLOVAKIA

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1993年 / 58卷 / 05期

关键词：

D O I：

10.1135/cccc19931087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective demethylation of the zwitterion 9-Me2S-7,8-C2B9H11 by sodium naphthalenide in tetrahydrofuran led to the racemic 19-McS-7,8-C2B9H11]- ion. which could be partially resolved lo its (-)-enantiomer via the [(-)-1-Ph-1-Me3N-CHCH3]+ salt. Complexation of the ions with Co2+ and C5H5- afforded the (+/-)- and (+)-4-MeS-3-C5H5-1,2,3-C2CoB9H10 cobaltacarboranes, respectively. A partially resolved (-)-9-Me2S-7,8-C2B9H11 was obtained by re-methylation of the (-)-[9-MeS-7,8-C2B9H11]- ion.

引用

页码：1087 / 1092

页数：6

共 50 条

[1] Syntheses of (C5H9C5H4)2 LnCl(THF)n and Crystal Structures of [(C5H9C5H4)2SmCl(THF)]2 and [(C5H9C5H4)2ErCl]2
金玑洙
金钟声
卫革成
陈文启
ChineseScienceBulletin, 1993, (06) : 526 - 527
[2] SYNTHESES OF (C5H9C5H4)2 LNCL(THF)N AND CRYSTAL-STRUCTURES OF [(C5H9C5H4)2SMCL(THF)]2 AND [(C5H9C5H4)2ERCL]2
JIN, JZ
JIN, ZS
WEI, GC
CHEN, WQ
CHINESE SCIENCE BULLETIN, 1993, 38 (06): : 526 - 527
[3] SYNTHESIS OF 2 NEW COBALTABORANE COMPLEXES - 1-(ETA-C5H5)COB5H9 AND 2-(ETA-C5H5)COB9H13
WILCZYNSKI, R
SNEDDON, LG
INORGANIC CHEMISTRY, 1979, 18 (03) : 864 - 866
[4] Gas-phase clustering reactions of NO2-, C2H3NO2-, C2H4NO2-C2H5NO2- and C2H5NO4- with C2H5NO2
Wincel, H
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2004, 232 (02) : 185 - 194
[5] Formation of C9H2 and C10H2 from Reactions C3H + C6H2 and C4H + C6H2
Sun, Yi-Lun
Huang, Wen-Jian
Lee, Shih-Huang
JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 121 (51): : 9687 - 9697
[6] (C5H9C5H4)2LnCl·nTHF的合成及[（C5H9C5H4）2SmCl（THF）]2和[（C5H9C5H4）2ErCl]2的晶体结构
金玑洙
金钟声
卫革成
陈文启
科学通报, 1992, (18) : 1724 - 1725
[7] ALUMINOTITANIUM HYDRIDES [(C5H5]TI]2(H)(H2ALET2)(C10H8) AND [(C5H4)TIHALET2]2(C10H8)
GUGGENBE.LJ
TEBBE, FN
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (23) : 7870 - 7872
[8] THE ELECTRONIC-STRUCTURES OF [(C5H4-C6H5)CR(CO)3]-, [(C6H4COC6H5)CR(CO)3)-, [(C5H4CH2C6H5)CR(CO)3]-, [(C5H4C2H2C6H5)CR(CO)3]- AND (C6H5-C5H4)MN(CO)3, (C6H5COC5H4)MN(CO)3, (C6H5CH2C5H4)MN(CO)3, (C6H5C2H2C5H4)MN(CO)3
FITZPATRICK, NJ
GOGAN, NJ
SAYAL, PK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 301 (02) : C31 - C34
[9] Lithiation of the diaminopyridine protio-ligand MeC(2-C5H4N){CH2N(H) Mes}2 (Mes=2,4,6-C6H2Me3)
Ward, BD
Gade, LH
Mountford, P
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M472 - M474
[10] Calculations of the rate constants for the hydrogen abstraction reactions C2H3+CH4 → C2H4+CH3 and C2H3+C2H6 → C2H4+C2H5
Liu, GX
Li, ZS
Xiao, JF
Liu, JY
Fu, Q
Huang, XR
Sun, CC
Tang, AC
CHEMPHYSCHEM, 2002, 3 (07) : 625 - +

← 1 2 3 4 5 →