SYNTHESIS, CHARACTERIZATION AND STRUCTURE OF (N2H5)3MNX5 (X = CL AND BR)

被引：2

作者：

KUMAR, NRS ^{[1
]}

NETHAJI, M ^{[1
]}

PATIL, KC ^{[1
]}

机构：

[1] INDIAN INST SCI,DEPT INORGAN & PHYS CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1991年 / 24卷 / 04期

关键词：

HYDRAZINIUM CATION; MANGANESE COMPLEX; X-RAY STRUCTURE;

D O I：

10.1080/00958979109407893

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new hydrazinium complexes of manganese, (N2H5)3MnX5 (X = Cl and Br), have been prepared and characterized by analysis, infrared and visible spectra. The single crystal X-ray structure of the chloride complex has been determined. Only one of the three N2H+ 5cations is coordinated to the metal. In the anion, [Mn(N2H5)Cl5]2−, the coordination polyhedron around the manganese atom is a slightly distorted octahedron. © 1991, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：333 / 337

页数：5

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