CHARGE RECOMBINATION PROCESS OF ION-PAIR STATE PRODUCED BY EXCITATION OF CHARGE-TRANSFER COMPLEX IN ACETONITRILE SOLUTION - ESSENTIALLY DIFFERENT CHARACTER OF ITS ENERGY-GAP DEPENDENCE FROM THAT OF GEMINATE ION-PAIR FORMED BY ENCOUNTER BETWEEN FLUORESCER AND QUENCHER

被引：242
作者：
ASAHI, T [1 ]
MATAGA, N [1 ]
机构：
[1] OSAKA UNIV,FAC ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1989年 / 93卷 / 18期
关键词：
D O I：
10.1021/j100355a001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
引用
收藏
页码：6575 / 6578
页数：4
相关论文
共 20 条
[1]  
Foster R., 1969, ORGANIC CHARGE TRANS
[2]   RETURN ELECTRON-TRANSFER WITHIN GEMINATE RADICAL ION-PAIRS - OBSERVATION OF THE MARCUS INVERTED REGION [J].
GOULD, IR ;
EGE, D ;
MATTES, SL ;
FARID, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) :3794-3796
[3]   PHOTOINDUCED ELECTRON-TRANSFER IN PYROMELLITIMIDE-BRIDGED PORPHYRINS [J].
HARRISON, RJ ;
PEARCE, B ;
BEDDARD, GS ;
COWAN, JA ;
SANDERS, JKM .
CHEMICAL PHYSICS, 1987, 116 (03) :429-448
[4]   DIFFERENT ENERGY-GAP LAWS FOR THE 3 TYPES OF ELECTRON-TRANSFER REACTIONS IN POLAR-SOLVENTS [J].
KAKITANI, T ;
MATAGA, N .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (06) :993-995
[5]   ELECTRON TRANSFERS IN CHEMISTRY AND BIOLOGY [J].
MARCUS, RA ;
SUTIN, N .
BIOCHIMICA ET BIOPHYSICA ACTA, 1985, 811 (03) :265-322
[6]   IONIC PHOTO-DISSOCIATION OF ELECTRON-DONOR - ACCEPTOR SYSTEMS IN SOLUTION [J].
MASUHARA, H ;
MATAGA, N .
ACCOUNTS OF CHEMICAL RESEARCH, 1981, 14 (10) :312-318
[7]  
MATAGA N, 1987, ACTA PHYS POL A, V71, P767
[8]   THE BELL-SHAPED ENERGY-GAP DEPENDENCE OF THE CHARGE RECOMBINATION REACTION OF GEMINATE RADICAL ION-PAIRS PRODUCED BY FLUORESCENCE QUENCHING REACTION IN ACETONITRILE SOLUTION [J].
MATAGA, N ;
ASAHI, T ;
KANDA, Y ;
OKADA, T ;
KAKITANI, T .
CHEMICAL PHYSICS, 1988, 127 (1-3) :249-261
[9]   DYNAMICS OF AROMATIC HYDROCARBON CATION TETRACYANOETHYLENE ANION GEMINATE ION-PAIRS IN ACETONITRILE SOLUTION WITH IMPLICATIONS TO THE MECHANISM OF THE STRONGLY EXOTHERMIC CHARGE SEPARATION REACTION IN THE EXCITED SINGLET-STATE [J].
MATAGA, N ;
KANDA, Y ;
OKADA, T .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (17) :3880-3882
[10]   MECHANISMS OF THE STRONGLY EXOTHERMIC CHARGE SEPARATION REACTION IN THE EXCITED SINGLET-STATE - PICOSECOND LASER PHOTOLYSIS STUDIES ON AROMATIC HYDROCARBON TETRACYANOETHYLENE AND AROMATIC HYDROCARBON PYROMELLITIC DIANHYDRIDE SYSTEMS IN POLAR SOLUTIONS [J].
MATAGA, N ;
KANDA, Y ;
ASAHI, T ;
MIYASAKA, H ;
OKADA, T ;
KAKITANI, T .
CHEMICAL PHYSICS, 1988, 127 (1-3) :239-248
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