PHOTOELECTRON-SPECTRA OF CYCLOPOLYSILANES

被引：8
|
作者：
JANOSCHEK, R
HENGGE, E
STUGER, H
NYULASZI, L
机构：
[1] TECH UNIV BUDAPEST,INST ANORGAN CHEM,H-1521 BUDAPEST,HUNGARY
[2] GRAZ TECH UNIV,INST ANORGAN CHEM,A-8010 GRAZ,AUSTRIA
来源：
MONATSHEFTE FUR CHEMIE | 1991年 / 122卷 / 1-2期
关键词：
ABINITIO CALCULATIONS; CYCLOPOLYSILANES; PE-SPECTRA;
D O I：
10.1007/BF00815160
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
He (I) PE spectra of cyclopentasilane and cyclohexasilane show excellent agreement with STO-3 G+ ab initio calculations. The HOMO in both compounds is of sigma (SiSi) 3 p character. First IP's appear at 9.4 and 9.6 eV respectively.
引用
收藏
页码：31 / 34
页数：4
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