[NB(B(ETA-6-C6H5)2(C6H5)2)(ETA-2-H3CC2CH3)] - THE 1ST COMPOUND WITH BENT TETRAPHENYLBORATE AS 12-ELECTRON DONOR LIGAND

被引：23

作者：

CALDERAZZO, F

ENGLERT, U

PAMPALONI, G

ROCCHI, L

机构：

[1] DIPARTIMENTO CHIM & CHIM IND,VIA RISORGIMENTO 35,I-56126 PISA,ITALY

[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,W-5100 AACHEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 09期

关键词：

D O I：

10.1002/anie.199212351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The "counterion" BPh4- functions a sandwich ligand in the niobium(I) complex 1. This is confirmed by the X-ray structure analysis of 1a. The BPh4- complexes 1 are the first in which two of the four phenyl rings of the tetraphenylborate bind to one metal center. Such complexes could be important as model compounds for catalytic processes.

引用

页码：1235 / 1236

页数：2

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