STERIC EFFECTS IN HETEROBORANES .5. 1-PH-2-ME(3)SI-1,2-CLOSO-C2B10H10

被引：12

作者：

MCGRATH, TD ^{[1
]}

WELCH, AJ ^{[1
]}

机构：

[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S010827019400908X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of 1-phenyl-2-trimethylsilyl-1,2-dicarba-closo-dodecaborane(12), C11H24B10Si, has been determined crystallographically. The C-cage-C-cage distance is 1.708 (4) Angstrom, only slightly longer than in the 2-methyl analogue. However, in contrast to the 2-methyl and 2-bromo analogues, relief from steric congestion is afforded by a mutual 'bend back' of both the phenyl and trimethylsilyl groups, the latter involving deformation of valency angles both at Si and the C-cage atom to which it is attached.

引用

页码：651 / 654

页数：4

共 50 条

[1] STERIC EFFECTS IN HETEROBORANES .3. 1-PH-2-ME-1,2-CLOSO-C2B10H10
MCGRATH, TD
WELCH, AJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 646 - 649
[2] STERIC EFFECTS IN HETEROBORANES .6. 1-PH-2-(T)BUME(2)SI-1,2-CLOSO-C2B10H10
MCGRATH, TD
WELCH, AJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 654 - 657
[3] STERIC EFFECTS IN HETEROBORANES .4. 1-PH-2-BR-1,2-CLOSO-C2B10H(10)
MCGRATH, TD
WELCH, AJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 : 649 - 651
[4] STRUCTURE OF 1,2-DIPHENYLCARBABORANE, 1,2-PH2-1,2-CLOSO-C2B10H10
LEWIS, ZG
WELCH, AJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 705 - 710
[5] 1,2-Ph2-9-1-1,2-closo-C2B10H9 -: Steric effects in heteroboranes.: Part 24
McGrath, TD
Fox, MA
Welch, AJ
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : 487 - 488
[6] Are halocarboranes suitable for substitution reactions?: The case for 3-I-1,2-closo-C2B10H11:: Molecular orbital calculations, aryldehalogenation reactions, 11B NMR interpretation of closo-carboranes, and molecular structures of 1-Ph-3-Br-1,2-closo-C2B10H10 and 3-Ph-1,2-closo-C2B10H11
Viñas, C
Barberà, G
Oliva, JM
Teixidor, F
Welch, AJ
Rosair, GM
INORGANIC CHEMISTRY, 2001, 40 (26) : 6555 - 6562
[7] Unexpected formation of ruthenium(II) hydrides from a reactive dianiline precursor and 1,2-(Ph2P)2-1,2-closo-C2B10H10
Adams, Jeramie J.
Del Negro, Andrew S.
Arulsamy, Navamoney
Sullivan, B. Patrick
INORGANIC CHEMISTRY, 2008, 47 (06) : 1871 - 1873
[8] Application of the NOE experiment to the analysis of boron hydride derivatives:: confirming the assignments of the pseudocloso-complex [1,2-Ph2-3-{Cp*}-3,1,2-IrC2B9H9] (Cp* = η5-C5Me5) and the closo-compounds 1-Ph-1,2-C2B10H11 and 1-Ph-2-Me-1,2-C2B10H10
Reed, D
Welch, AJ
Cowie, J
Donohoe, DJ
Parkinson, JA
INORGANICA CHIMICA ACTA, 1999, 289 (1-2) : 125 - 133
[9] 1,2-Ph2-9-I-1,2-closo-C2B10H9
McGrath, Thomas D.
Fox, Mark A.
Welch, Alan J.
Acta Crystallographica, Section C: Crystal Structure Communications, 2000, 56 (04) : 487 - 488
[10] Haloaryl carbaboranes -: 2.: Synthesis and characterisation of haloaryl-closo-carbaboranes.: Crystal structures of 1-(4-BrC6F4)-2-R-1,2-closo-C2B10H10 (R = Me, Ph, But)
Thomas, RL
Welch, AJ
POLYHEDRON, 1999, 18 (14) : 1961 - 1968

← 1 2 3 4 5 →