NEUTRAL AND IONIC ALKYLGLUCOPYRANOSIDES - SYNTHESIS, CHARACTERIZATION AND PROPERTIES

被引：29
作者：
FOCHER, B
SAVELLI, G
TORRI, G
机构：
[1] UNIV AQUILA, DIPARTIMENTO CHIM INGN CHIM & MAT, I-67100 LAQUILA, ITALY
[2] IST CHIM & BIOCHIM G RONZONI, I-20133 MILAN, ITALY
来源：
CHEMISTRY AND PHYSICS OF LIPIDS | 1990年 / 53卷 / 2-3期
关键词：
alkylglucopyranosides; characterisation; glycolipids; properties; synthesis;
D O I：
10.1016/0009-3084(90)90040-X
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The synthesis of neutral and ionic α- and β-d-alkylglucopyranosides bearing hydrocarbon chains of different length (C8-C16 was performed by Fischer, Koenigs-Knorr and Schmidt methods. Cationic derivatives were obtained via tosylates as intermediates. The physico-chemical properties of products were investigated both in solution and at solid state by various techniques (quasi-elastic dynamic light scattering, differential scanning calorimetry. FTIR and CP-MAS spectroscopy and X-ray diffractometry). Above the critical micellar concentration, micellar or bilayer microagregates were obtained depending on the configuration of the anomeric centre of alkylglucopyranoside. Molecular packing and hydrogen bonds between saccharide heads in the solid state also depended on the aliphatic chain length and on the anomeric configuration. © 1990.
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页码：141 / 155
页数：15
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