A PRIMER FOR VALENCE-BOND MIXING AND AVOIDED CROSSING - GENERAL PARADIGMS IN CHEMICAL-REACTIVITY

被引:11
|
作者
SHAIK, S [1 ]
机构
[1] HEBREW UNIV JERUSALEM, FRITZ HABER CTR MOLEC DYNAM, IL-91904 JERUSALEM, ISRAEL
基金
新加坡国家研究基金会;
关键词
D O I
10.1016/0167-7322(94)00753-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A curve crossing diagram is a model for the construction of energy profiles by means of valence bond mixings and avoided crossings. The key principles of the model and its applications to reactivity patterns. reaction mechanisms and structural trends, are reviewed.
引用
收藏
页码:49 / 79
页数:31
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