SPEEDS OF SOUND, ISENTROPIC COMPRESSIBILITIES, AND EXCESS VOLUMES OF BINARY-MIXTURES .3. DI-N-ALKYLAMINES WITH CYCLOHEXANE AND BENZENE

被引:17
|
作者
OSWAL, S
OSWAL, P
PATEL, AT
机构
[1] Department of Chemistry, South Gujarat University
[2] Department of Chemistry, Government College, Pratapgarh
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关键词
D O I
10.1021/je00019a015
中图分类号
O414.1 [热力学];
学科分类号
摘要
Isentropic compressibilities K-S, excess isentropic compressibilities K-S(E), and excess volumes V-E have been determined from speeds of sound U and densities rho for six binary mixtures of butylamine, dihexylamine, and dioctylamine with cyclohexane or benzene as a function of the mole fraction at 303.15 K. Variable-degree polynomials have been fitted to the results. V-E and K-S(E) values are positive over the entire range of composition for all mixtures except cyclohexane + dioctylamine which have negative K-S(E).
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页码:607 / 610
页数:4
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