METHANOL CONVERSION TO HYDROCARBONS OVER H-ZSM-5 - FURTHER EVIDENCE FOR THE ROLE OF NO

被引:2
|
作者
HUTCHINGS, GJ
VANRENSBURG, LJ
COPPERTHWAITE, RG
HUNTER, R
DWYER, J
DEWING, J
机构
[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA
[2] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND
[3] UNIV WITWATERSRAND,DEPT CHEM,CATALYSIS RES PROGRAMME,JOHANNESBURG 2050,SOUTH AFRICA
关键词
D O I
10.1007/BF00764865
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Inhibition of the methanol to gasoline reaction induced by co-feeding of nitric oxide is compared and contrasted with inhibition by ammonia. It is concluded that NO does not act as a catalyst poison by being converted to NH3. A mechanism for inhibition of the reaction by NO based on the Barton reaction is proposed. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.
引用
收藏
页码:7 / 14
页数:8
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