INFLUENCE OF Bi3+ IONS ON KINETICS OF LEAD DIOXIDE ELECTRODEPOSITION FROM METHANESULFONATE ELECTROLYTES

被引：3
|
作者：
Shmychkova, Olesia [1 ]
Magamedova, Amina [1 ]
Girenko, Dmitriy [1 ]
Luk'yanenko, Tatiana [1 ]
Velichenko, Alexander [1 ]
机构：
[1] Ukrainian State Univ Chem Technol, 8,Gagarin Ave, Dnepropetrovsk 49005, Ukraine
来源：
CHEMISTRY & CHEMICAL TECHNOLOGY | 2013年 / 7卷 / 04期
关键词：
lead dioxide; methanesulfonate electrolyte; electrodeposition; kinetics; bismuth ions;
D O I：
10.23939/chcht07.04.365
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Influence of bismuth ions on kinetics of lead dioxide electrodeposition from methanesulfonate electrolytes on Pt-electrode was studied. Experimental results are interpreted to be consistent with the mechanism proposed previously for lead dioxide electrodeposition in literature. The presence of bismuth ions in the electrodeposition solution causes decreasing rate constants of lead dioxide formation due to additive adsorption.
引用
收藏
页码：365 / 368
页数：4
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