NEW SYNTHESIS OF ALIPHATIC ISOTHIOCYANATES FROM PRIMARY AMINES, CONVENIENT FOR IN-SITU USE

被引：31
|
作者：
BOAS, U [1 ]
JAKOBSEN, MH [1 ]
机构：
[1] UNIV COPENHAGEN,DEPT GEN & ORGAN CHEM,CTR MED BIOTECHNOL,HC ORSTED INST,DK-2100 COPENHAGEN,DENMARK
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期
关键词：
D O I：
10.1039/c39950001995
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.
引用
收藏
页码：1995 / 1996
页数：2
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