ENVIRONMENT FRIENDLY SPIN-CATALYSIS FOR DIOXYGEN ACTIVATION

被引：0
|
作者：
Minaev, Boris [1 ]
机构：
[1] Royal Inst Technol, Sch Biotechnol, Theoret Chem, SE-10691 Stockholm, Sweden
来源：
CHEMISTRY & CHEMICAL TECHNOLOGY | 2010年 / 4卷 / 01期
关键词：
ferric alkylperoxo complexes; hemoglobin; myoglobin; cytochrome P450; Fe(IV)-oxo compound I; glucose oxidase; spin-orbit coupling; high-spin; low-spin transition;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Catalysis of controlled selective oxidation of hydrocarbons utilizing molecular oxygen, being of great potential for the environmental friendly chemical industry, has to be designed by analogy with biological enzymatic reactions. Catalysis of oxidation of hydrocarbons by paramagnetic dioxygen avoiding a classical free radical chain mechanism needs to overcome spin prohibition. Classification of spin catalysis in biological activation of dioxygen is presented in this review and discussed in connection with known industrial processes. A few important examples are highlighted to illustrate the role of spin effects in O-2 binding to myoglobin, glucose oxidases, cytochrome P450, horse reddish peroxidase, and non-heme irone complexes.
引用
收藏
页码：1 / 16
页数：16
相关论文
共 50 条
  • [1] Spin-catalysis phenomena
    Minaev, BF
    Agren, H
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1996, 57 (03) : 519 - 532
  • [2] Spin-philicity and spin-donicity as auxiliary concepts to quantify spin-catalysis phenomena
    Pérez, P
    Andrés, J
    Safont, VS
    Tapia, O
    Contreras, R
    JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (21): : 5353 - 5357
  • [3] SPIN-ORBIT-COUPLING INDUCED CHEMICAL-REACTIVITY AND SPIN-CATALYSIS PHENOMENA
    MINAEV, BF
    AGREN, H
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1995, 60 (03) : 339 - 371
  • [4] Homogeneous catalysis - On the trail of dioxygen activation
    Hill, CL
    Weinstock, IA
    NATURE, 1997, 388 (6640) : 332 - 333
  • [5] Paramagnetic exchange spin-catalysis of the cis-trans isomerization of substituted ethylenes
    Plachkevytch, O
    Minaev, B
    Agren, H
    JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (20): : 8308 - 8315
  • [6] Bioinspired catalytic systems for dioxygen activation and catalysis
    Avenier, F.
    Guillot, R.
    Aukauloo, A.
    Mahy, J. P.
    Herrero, C.
    Leibl, W.
    Desbois, A.
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2014, 19 : S553 - S553
  • [7] Life as aerobes: are there simple principles for enzyme catalysis of dioxygen activation?
    Klinman, JP
    JOURNAL OF INORGANIC BIOCHEMISTRY, 1999, 74 (1-4) : 4 - 4
  • [8] On the activation of dioxygen
    Manchot, W
    JUSTUS LIEBIGS ANNALEN DER CHEMIE, 1901, 314 (1/3): : 177 - 199
  • [9] Reactivity models for dinuclear iron metalloenzymes - Oxygen atom transfer catalysis and dioxygen activation
    Stassinopoulos, A
    Mukerjee, S
    Caradonna, JP
    MECHANISTIC BIOINORGANIC CHEMISTRY, 1995, 246 : 83 - 120
  • [10] Selective spin injection of g-SiC6 monolayer for dioxygen activation
    Cao, Xinrui
    Xiang, Yaowei
    Wu, Shunqing
    Zhu, Zi-Zhong
    Li, Xiao-Fei
    APPLIED SURFACE SCIENCE, 2023, 613
12345