CHEMISTRY OF MU-ETA(1)-ETA(2)ETA(ALPHA,BETA)-BUTADIYNYLS - CHAIN EXTENSION ON C-4 POLYCARBON LIGANDS

被引：18

作者：

BLENKIRON, P ^{[1
]}

PILETTE, D ^{[1
]}

CORRIGAN, JF ^{[1
]}

TAYLOR, NJ ^{[1
]}

CARTY, AJ ^{[1
]}

机构：

[1] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,DEPT CHEM,WATERLOO,ON N2L 3G1,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 21期

关键词：

D O I：

10.1039/C39950002165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The binuclear butadiynyl compounds Ru-2(CO)(6)(mu-eta(1),eta(alpha,beta)(2)-C=C-C=CR)(mu-PPh(2)) (R = Bu(t) 1a or Ph 1b), with one pi-coordinated and one free triple bond, synthesised via thermolysis of Ru-3(CO)(11) (PPh(2)C=C-C=CR), react with NEt(2)H to generate the novel diethylaminobutatriene complexes Ru-2(CO)(6)[mu-eta(1),eta(1)-Et(2)N=C=C=C=C(H)R](mu-PPh(2)) (R = Bu(t) 2a or Ph 2b) in high yields: the molecular structures of la and 2a are determined.

引用

页码：2165 / 2166

页数：2

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