It has been suggested that excitation of poly(p-phenylene vinylene) (PPV) by photons above the absorption edge produces principally polaron pairs or split excitons. We show that such polaron pairs can account very well for the peaks in the observed picosecond photoinduced absorption, the width of the absorption, and other phenomena associated with photon absorption in PPV.
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Tokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, JapanTokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, Japan
Natori, Itaru
Natori, Shizue
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Tokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, JapanTokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, Japan
Natori, Shizue
Ogino, Kenji
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Tokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, JapanTokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, Japan