N-[ALPHA-(ORTHO-METHOXYARYL AND PARA-METHOXYARYL)ALKYL]BENZOTRIAZOLES - PREPARATION AND USE IN SYNTHESIS

被引：26
|
作者：
KATRITZKY, AR
LAN, XF
LAM, JN
机构：
[1] Department of Chemistry, University of Florida, Gainesville, Florida
来源：
CHEMISCHE BERICHTE | 1991年 / 124卷 / 08期
关键词：
LITHIATION; GRIGNARD REACTION; CONDENSATION; ARYL ETHERS; DIARYLMETHANES;
D O I：
10.1002/cber.19911240819
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Methoxybenzenes and -naphthalenes are benzotriazolylmethylated in the para-position or if this is blocked in an ortho-position. The methylene groups in the products are readily substituted by electrophiles via the lithiated derivatives. Displacement of the benzotriazole group can be effected by organometallic reagents or by electron-rich benzoid compounds to afford a versatile method for the synthesis of substituted aryl ethers.
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页码：1819 / 1826
页数：8
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