THERMOCHEMISTRY OF COPPER(II) ION SOLVATION IN AQUEOUS-ORGANIC SOLVENTS

被引：5
|
作者：
MIKHEEV, SV
SHARNIN, VA
SHORMANOV, VA
TALANOVA, MN
机构：
[1] State Academy of Chemistry and Technology, Ivanovo
来源：
JOURNAL OF THERMAL ANALYSIS | 1995年 / 45卷 / 04期
关键词：
COPPER(II) CHLORIDE; HEAT EFFECTS OF DISSOLUTION; ION SOLVATION; THERMOCHEMISTRY; WATER-ORGANIC SOLVENTS;
D O I：
10.1007/BF02548886
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The integral heat effects of CuCl2 dissolution in aqueous DMSO, aqueous ethanol and aqueous acetone solutions at 298.15 K in the electrolyte concentration range 0.001-0.01 M were measured by means of calorimetry. Delta H-sol(0) values were obtained by extrapolation to zero electrolyte concentration. Literature data were used to determine the thermodynamic characteristics of CU2+ transfer from water to aqueous organic solvents.
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页码：715 / 720
页数：6
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