SYNTHESIS OF A CROWN-ETHER FUNCTIONALIZED PHOSPHINE AND ITS NICKEL(II), PALLADIUM(II) AND PLATINUM(II) COMPLEXES

被引：11
|
作者：
SERINDAG, O
机构：
[1] Çukurova University Science and Arts Faculty, Chemistry Department
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1995年 / 25卷 / 02期
关键词：
D O I：
10.1080/15533179508218223
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of 4'-aminobenzo-15-crown-5 (1) (Figure 1) with diphenylphosphine in the presence of formaldehyde or with the phosphonium salt [Ph(2)P(CH2OH)(2)]Cl in the presence of triethylamine gives a novel aminomethylphosphine (2). Nickel(II), palladium(II) and platinum(II) complexes of (2) have been synthesized and characterized by means of their P-31 and H-1 NMR and mass spectra and microanalytical data.
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页码：327 / 335
页数：9
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