Synthesis of Tris(4-Methoxyphenyl) Phenylsilane Using Phenylsilane and 4-Iodo Anisole Catalyzed by Palladium Complex

被引：0
|
作者：
Lesbani, Aldes [1 ]
Mohadi, Risfidian [1 ]
Eliza [1 ]
Mardiyanto [2 ]
机构：
[1] Univ Sriwijaya, Fac Math & Nat Sci, Dept Chem, Ogan Ilir 30662, Sumatera Selata, Indonesia
[2] Univ Sriwijaya, Fac Math & Nat Sci, Dept Pharm, Ogan Ilir 30662, Sumatera Selata, Indonesia
来源：
MAKARA JOURNAL OF SCIENCE | 2014年 / 18卷 / 01期
关键词：
4-iodoanisole; palladium; phenylsilane; tris(4-methoxyphenyl)phenylsilane;
D O I：
10.7454/mss.v18i1.3051
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The synthesis of tris(4-methoxyphenyl) phenylsilan through the coupling reaction of phenylsilane and 4-iodoanisole using palladium tertiary tributylphosphine as a catalyst was carried out through the determination of the base, solvent, and reaction time. The results showed that tris(4-methoxyphenyl) phenylsilane can be synthesized to form maximum yield using 1,4-diazabicyclo[2,2,2] octane (DABCO) as a base, tetrahydrofuran as a solvent, and a 5-day reaction time. The highest yield of tris(4-methoxyphenyl)phenylsilane was 35%.
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收藏
页码：13 / 18
页数：6
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