1,5-INTRAMOLECULAR VS 1,6-INTRAMOLECULAR HOMOLYTIC AROMATIC-SUBSTITUTION BY VINYL RADICALS

被引：32
|
作者：
CITTERIO, A [1 ]
SEBASTIANO, R [1 ]
MARONATI, A [1 ]
SANTI, R [1 ]
BERGAMINI, F [1 ]
机构：
[1] IST GUIDO DONEGANI SPA,I-28100 NOVARA,ITALY
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 13期
关键词：
D O I：
10.1039/c39940001517
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Manganese(III) acetate oxidation of substituted diethyl benzylmalonates in the presence of alkynes affords tetrahydronaphthalene derivatives 3, 6, 7 and spiro [4,5]decatriene derivatives 4 or 5, through competitive 1,5 and 1,6 intramolecular aromatic substitution by vinyl radicals.
引用
收藏
页码：1517 / 1518
页数：2
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