FORMATION OF BILAYER STRUCTURE IN ORGANIC-SOLVENTS FROM AMPHIPHILES DUE TO INTERPEPTIDE HYDROGEN-BONDING

被引:22
|
作者
YAMADA, N
KOYAMA, E
KANEKO, M
SEKI, H
OHTSU, H
FURUSE, T
机构
[1] CHIBA UNIV, CTR CHEM ANAL, INAGE KU, CHIBA 263, JAPAN
[2] NATL INST RADIOL SCI, DIV PHYSIOL & PATHOL, INAGE KU, CHIBA 263, JAPAN
关键词
D O I
10.1246/cl.1995.387
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In order to produce molecular organization in a wide variety of media, novel amphiphiles containing an associative tripeptide moiety were prepared. Electron microscopy revealed bilayer formation from the amphiphile not only in water but also in nonpolar organic solvents. H-1-NMR spectroscopy gave direct evidence of interpeptide hydrogen bonding in the aggregate.
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页码:387 / 388
页数:2
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