THE LITHIUM POLYMER ELECTROLYTE INTERFACE

被引:18
|
作者
CHRISTIE, AM [1 ]
LISOWSKAOLEKSIAK, A [1 ]
VINCENT, CA [1 ]
机构
[1] UNIV ST ANDREWS,SCH CHEM,CTR ELECTROCHEM & MAT SCI,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
关键词
MICROELECTRODE; POLYMER ELECTROLYTE; LITHIUM DEPOSITION; VOLTAMMETRY; CHRONOAMPEROMETRY;
D O I
10.1016/0013-4686(95)00204-R
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Kinetics and mechanisms for the electrodeposition of lithium from liquid and solid polymer electrolytes formed from lithium salts or from lithium salt complexes have been studied using chronoamperometric and cyclic voltammetric methods at a microelectrode. The type of nucleation and crystal growth process was determined as a function of polymer electrolyte composition. Exchange current densities, coulombic stripping efficiencies and lithium corrosion rates were evaluated.
引用
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页码:2405 / 2411
页数:7
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