SYNTHESIS OF NOVEL PI-CONJUGATED POLYMER CONTAINING PORPHYRINS

被引:19
|
作者
AOTA, H [1 ]
ITAI, Y [1 ]
MATSUMOTO, A [1 ]
KAMACHI, M [1 ]
机构
[1] OSAKA UNIV, FAC SCI, DEPT MACROMOLEC SCI, TOYONAKA, OSAKA 560, JAPAN
关键词
D O I
10.1246/cl.1994.2043
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymers containing porphyrins were synthesized from pyrrole, 1-dodecanal, and (2-formyl-5,10,15,20-tetraphenylporphyrinato)oxovanadium(IV) or 2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-5,10-dipyrrylporphine. The number-average molecular weights of the resulting polymers were about 3000. NMR and absorption spectral data show the formation of the pi-conjugated polymer.
引用
收藏
页码:2043 / 2046
页数:4
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