ESR TOMOGRAPHY OF RADIATION-INDUCED OXIDATION OF POLYPROPYLENE

被引：0
|
作者：
DEGTYAREV, EN
KIRYUSHKIN, SG
SMIRNOV, AI
YAKIMCHENKO, OE
机构：
来源：
HIGH ENERGY CHEMISTRY | 1993年 / 27卷 / 04期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The method of ESR tomography with a modulated gradient of a nonuniform magnetic field was used to obtain the spatial distribution of RO2 radicals in isotactic polypropylene exposed to gamma irradiation in air, and the parameter a = (k(ef)/D(O2))0.5 was determined. The possibility of predicting the change in the mechanical properties of polymers during radiation-induced oxidation is discussed.
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页码：274 / 278
页数：5
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