1,4-BIS(TRICHLOROMETHYL)BENZENE CHLORINATION IN CHLOROSULFONIC ACID

被引：0
|
作者：
SIMONOV, VD
VORONKOVA, LV
POPOVA, NF
IVANOV, VI
NUGUMANOVA, GM
机构：
来源：
KHIMICHESKAYA PROMYSHLENNOST | 1983年 / 06期
关键词：
CHEMICAL REACTIONS - Chlorination;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
On the basis of experimental and available literature data, it is concluded that the conversion of the trichloromethyl groups in 1,4-bis(trichloromethyl)benzene into chloroanhydride groups is accompanied by the formation of pyrosulfurylchloride. These variants of the sequence of reactions occurring during the chlorination of 1,4-bis (trichloromethyl)benzene by gaseous chlorine in a chlorosulfonic acid medium are proposed: the conversion of the trichloromethyl groups into chloranhydride groups with subsequent chlorination into a nucleus, chlorination into a nucleus with subsequent conversion of the trichloromethyl groups into chloroanhydride groups, and simultaneous chlorination and hydrolysis of 1,4-bis(trichloromethyl) benzene.
引用
收藏
页码：334 / 336
页数：3
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