STEREOSELECTIVE SYNTHESIS OF METHYL EPIJASMONATE

被引：21

作者：

KITAHARA, T ^{[1
]}

WARITA, Y ^{[1
]}

ABE, M ^{[1
]}

SEYA, M ^{[1
]}

TAKAGI, Y ^{[1
]}

MORI, K ^{[1
]}

机构：

[1] T HASEGAWA CO LTD,KAWASAKI RES CTR,NAKAHARA KU,KAWASAKI 211,JAPAN

来源：

AGRICULTURAL AND BIOLOGICAL CHEMISTRY | 1991年 / 55卷 / 04期

关键词：

D O I：

10.1080/00021369.1991.10870689

中图分类号：

S3 [农学（农艺学）];

学科分类号：

0901 ;

摘要：

Methyl epijasmonate (1) was stereoselectively synthesized from 3-hydroxymethylcyclopentanone (7). The intramolecular alkylation of bromoketone (8) or (9) was the key step to exclusively afford thermodynamically more stable oxahydrindanone (10) or (11). Synthesis was achieved in a 6% overall yield in 12 steps from (7).

引用

页码：1013 / 1017

页数：5

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