REACTIONS OF FLUOROBENZENE TRICARBONYLCHROMIUM COMPLEXES WITH ANIONS FROM SCHIFF-BASES OF ALPHA-AMINO ESTERS - ENANTIOSELECTIVE SYNTHESIS OF ALPHA-ARYL AMINO-ACIDS

被引：33
|
作者：
CHAARI, M [1 ]
JENHI, A [1 ]
LAVERGNE, JP [1 ]
VIALLEFONT, P [1 ]
机构：
[1] UNIV MONTPELLIER 2,SYNTH & ETUD PHYSICOCHIM AMINOACIDES & PEPTIDES LAB,URA 468,PLACE E BATAILLON,F-34095 MONTPELLIER 5,FRANCE
来源：
TETRAHEDRON | 1991年 / 47卷 / 26期
关键词：
D O I：
10.1016/S0040-4020(01)86468-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report here a convenient synthesis of alpha-substituted aryl amino acids via the addition of alpha-imino esters to fluorobenzene tricarbonylchromium complexes. Optically pure alpha-aryl amino acids have been prepared by enantioselective substitution of fluorobenzene complexes using Schiff bases of L-alanine, leucine and valine methyl esters and (1R, 2R, 5R)-2-hydroxypinan-3-one.
引用
收藏
页码：4619 / 4630
页数：12
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