SELF-ASSEMBLED MONOLAYERS OF ALKANETHIOLS CONTAINING A POLAR AROMATIC GROUP - EFFECTS OF THE DIPOLE POSITION ON MOLECULAR PACKING, ORIENTATION, AND SURFACE WETTING PROPERTIES

被引：225
|
作者：
EVANS, SD
URANKAR, E
ULMAN, A
FERRIS, N
机构：
[1] EASTMAN KODAK CO,CORP RES LABS,ROCHESTER,NY 14650
[2] EASTMAN KODAK CO,DIV ANALYT TECHNOL,ROCHESTER,NY 14650
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 11期
关键词：
D O I：
10.1021/ja00011a010
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of incorporating aromatic groups into self-assembled alkanethiol monolayers was studied using a variety of techniques including ellipsometry, wetting, reflection-absorption FTIR, surface (contact) potential, and surface enhanced Raman spectroscopy (SERS). The quality of the monolayers produced was found to be dependent on both the size of the dipole introduced into the film and the length of the aliphatic chain above the aromatic group.
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页码：4121 / 4131
页数：11
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